Vitrifying ZIF-4 and ZIF-62 drops the simulated Li-ion migration barrier from about 0.35 eV to 0.16 eV and switches anisotropic cage-hopping transport into faster, isotropic Fickian diffusion.
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Fast Isotropic Li-Ion Diffusion in Zeolitic Imidazolate Framework Glass Electrolytes for Batteries
Vitrifying ZIF-4 and ZIF-62 drops the simulated Li-ion migration barrier from about 0.35 eV to 0.16 eV and switches anisotropic cage-hopping transport into faster, isotropic Fickian diffusion.