Marcus decreasing rates and Rehm-Weller saturation emerge as nonadiabatic and adiabatic limits of the same two-level quantum Hamiltonian, reproducing experimental data with realistic reorganization energies and couplings.
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Resolving the Marcus-Rehm-Weller Paradox in Electron Transfer
Marcus decreasing rates and Rehm-Weller saturation emerge as nonadiabatic and adiabatic limits of the same two-level quantum Hamiltonian, reproducing experimental data with realistic reorganization energies and couplings.