A Rayleigh-quotient-based thermodynamic geometry reformulates relaxation dynamics as entropic stiffness versus frictional dissipation, with linear vanishing of the slow relaxation rate near the critical temperature in a van der Waals gas.
Schl¨ ogl, Thermodynamic metric and stochastic mea- sures, Zeitschrift f¨ ur Physik B Condensed Matter59, 449 (1985)
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Thermodynamic Geometry of Relaxation
A Rayleigh-quotient-based thermodynamic geometry reformulates relaxation dynamics as entropic stiffness versus frictional dissipation, with linear vanishing of the slow relaxation rate near the critical temperature in a van der Waals gas.