XMCD data on cubic Laves phases reveal finite Ni magnetic moments, crystal-field suppressed Nd and Pr moments, and composition-tunable mixed-valent Ce states with localized 4f configurations.
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Ni substitution in NdCo2-xNix lowers cubic-tetragonal and tetragonal-orthorhombic transition temperatures, suppresses the orthorhombic phase for x >= 0.5, reduces magnetic moment, and decreases adiabatic temperature change from 6.3 K to 4.9 K at 20 T.
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Electronic and magnetic properties of light rare-earth cubic Laves compounds derived from XMCD experiments
XMCD data on cubic Laves phases reveal finite Ni magnetic moments, crystal-field suppressed Nd and Pr moments, and composition-tunable mixed-valent Ce states with localized 4f configurations.
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Influence of Ni substitution on the phase transitions and magnetocaloric effect of NdCo2 at cryogenic temperatures
Ni substitution in NdCo2-xNix lowers cubic-tetragonal and tetragonal-orthorhombic transition temperatures, suppresses the orthorhombic phase for x >= 0.5, reduces magnetic moment, and decreases adiabatic temperature change from 6.3 K to 4.9 K at 20 T.