Lanthanide type and preparation atmosphere control oxygen-vacancy clustering and short-range ordering in UO2, and in gadolinium-doped UO2 a subnano bixbyite-like Ia-3 domain forms while the crystal stays globally fluorite.
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Non-stoichiometric and Subnano-heterogeneous Ln-incorporated UO2: its defect chemistry and thermal oxidation
Lanthanide type and preparation atmosphere control oxygen-vacancy clustering and short-range ordering in UO2, and in gadolinium-doped UO2 a subnano bixbyite-like Ia-3 domain forms while the crystal stays globally fluorite.