For membrane-bound receptors, the paper derives spatial versions of Michaelis-Menten, substrate competition, competitive inhibition, and uncompetitive inhibition rate laws, showing well-mixed formulas overestimate influx when receptor trapping is strong.
Sharma, and David B
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Reaction kinetics of membrane receptors: a spatial modeling approach
For membrane-bound receptors, the paper derives spatial versions of Michaelis-Menten, substrate competition, competitive inhibition, and uncompetitive inhibition rate laws, showing well-mixed formulas overestimate influx when receptor trapping is strong.