A designed transverse-stiffness ridge in a Chesnavich-type model creates a deep entropic bottleneck that gates inner-well capture from 57% to 15% and displaces roaming outward.
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An entropic bottleneck, dynamical gating, and outward redistribution of roaming in a designed Chesnavich-type model
A designed transverse-stiffness ridge in a Chesnavich-type model creates a deep entropic bottleneck that gates inner-well capture from 57% to 15% and displaces roaming outward.