IR absorbance analysis of thioether-linked dimers shows long-axis order increasing slowly in the nematic phase then reversing in the twist-bend phase due to tilt, with growing biaxial order matching helical director deformation and antiparallel dipole correlations at the transition.
Salamończyk, R.J
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Structure of the twist-bend nematic phase with respect to the orientational molecular order of the thioether-linked dimers
IR absorbance analysis of thioether-linked dimers shows long-axis order increasing slowly in the nematic phase then reversing in the twist-bend phase due to tilt, with growing biaxial order matching helical director deformation and antiparallel dipole correlations at the transition.