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Crystal structure and absence of magnetic order in single crystalline RuO$_2$

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abstract

RuO$_2$ was considered for a long time to be a paramagnetic metal with an ideal rutile-type structure down to low temperatures, but recent studies on single-crystals claimed evidence for antiferromagnetic order and some symmetry breaking in the crystal structure. We have grown single-crystals of RuO2 by vapor transport using either O$_2$ or TeCl$_4$ as transport medium. These crystals exhibit metallic behavior following a $T^2$ low-temperature relation and a small paramagnetic susceptibility that can be attributed to Pauli paramagnetism. Neither the conductance nor the susceptibility measurements yield any evidence for a magnetic or a structural transition between 300K and $\sim$4 K. Comprehensive single-crystal diffraction studies with neutron and X-ray radiation reveal the rutile structure to persist until 2K in our crystals, and show nearly perfect stoichiometry. Previous observations of symmetry forbidden reflections can be attributed to multiple diffraction. Polarized single-crystal neutron diffraction experiments at 1.6K exclude the proposed antiferromagnetic structures with ordered moments larger than 0.01 Bohr magnetons.

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representative citing papers

Effects of altermagnetic order, strain and doping in RuO$_2$

cond-mat.mtrl-sci · 2025-02-13 · conditional · novelty 6.0

Optical reflectance, ellipsometry, and Raman data plus DFT indicate bulk RuO2 is best described as nonmagnetic, with altermagnetic order only potentially stabilized by specific epitaxial strain.

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  • Effects of altermagnetic order, strain and doping in RuO$_2$ cond-mat.mtrl-sci · 2025-02-13 · conditional · none · ref 50 · internal anchor

    Optical reflectance, ellipsometry, and Raman data plus DFT indicate bulk RuO2 is best described as nonmagnetic, with altermagnetic order only potentially stabilized by specific epitaxial strain.