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Entropy production as correlation between system and reservoir

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abstract

We derive an exact (classical and quantum) expression for the entropy production of a finite system placed in contact with one or several finite reservoirs each of which is initially described by a canonical equilibrium distribution. Whereas the total entropy of system plus reservoirs is conserved, we show that the system entropy production is always positive and is a direct measure of the system-reservoir correlations and/or entanglements. Using an exactly solvable quantum model, we illustrate our novel interpretation of the Second Law in a microscopically reversible finite-size setting, with strong coupling between system and reservoirs. With this model, we also explicitly show the approach of our exact formulation to the standard description of irreversibility in the limit of a large reservoir.

fields

quant-ph 1

years

2026 1

verdicts

UNVERDICTED 1

representative citing papers

Emergence of Thermodynamics from Equilibration in Isolated Quantum Systems

quant-ph · 2026-06-27 · unverdicted · novelty 6.0

Any continuously differentiable function of equilibrating expectation values equilibrates, implying subsystem entropy and conjugate variables equilibrate and total entropy is dynamically maximized under local conservation in bipartite isolated quantum systems.

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  • Emergence of Thermodynamics from Equilibration in Isolated Quantum Systems quant-ph · 2026-06-27 · unverdicted · none · ref 15 · internal anchor

    Any continuously differentiable function of equilibrating expectation values equilibrates, implying subsystem entropy and conjugate variables equilibrate and total entropy is dynamically maximized under local conservation in bipartite isolated quantum systems.