Derives approximate parabolic melting-line equations from a modified Clausius-Clapeyron relation that incorporates volume-dependent latent heat arising from anharmonic contributions to the solid's isobaric heat capacity.
(10) is: ๐(๐๐) โ ๐ ๐ ๐๐ โ ๐1 ๐ ๐โ๐๐๐ + ๐2 (13) where ๐1 and ๐2 are integration constants
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Theory of melting lines with a variable enthalpy of fusion
Derives approximate parabolic melting-line equations from a modified Clausius-Clapeyron relation that incorporates volume-dependent latent heat arising from anharmonic contributions to the solid's isobaric heat capacity.