Simulations reconstruct sulfur's polymerization phase diagram, showing the lambda-transition temperature decreasing with pressure until merging with the melting line at a critical point, with polymerization emerging from the crystalline phase beyond it.
Behler, Atom-centered symmetry functions for construct- ing high-dimensional neural network potentials, The Journal of Chemical Physics134(2011)
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Pressure-Temperature Phase Diagram and $\lambda$-Transition in Liquid Sulfur
Simulations reconstruct sulfur's polymerization phase diagram, showing the lambda-transition temperature decreasing with pressure until merging with the melting line at a critical point, with polymerization emerging from the crystalline phase beyond it.