A capillary-plus-equation-of-state stability analysis shows that thick films in open pores are chemically unstable except near perfect wetting, while closed pores sustain a richer set of metastable and stable structures.
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Thermodynamic stability of droplets, bubbles and thick films in open and closed pores
A capillary-plus-equation-of-state stability analysis shows that thick films in open pores are chemically unstable except near perfect wetting, while closed pores sustain a richer set of metastable and stable structures.