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Excited-State-Specific Kohn-Sham Formalism for the Asymmetric Hubbard Dimer

physics.chem-ph · 2024-12-19 · conditional · novelty 7.0

The first excited state of the asymmetric Hubbard dimer is not non-interacting v-representable, but becomes complex-v-representable via analytic continuation; state-specific Kohn-Sham calculations with approximate functionals can yield spurious stationary solutions.

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  • Excited-State-Specific Kohn-Sham Formalism for the Asymmetric Hubbard Dimer physics.chem-ph · 2024-12-19 · conditional · none · ref 5

    The first excited state of the asymmetric Hubbard dimer is not non-interacting v-representable, but becomes complex-v-representable via analytic continuation; state-specific Kohn-Sham calculations with approximate functionals can yield spurious stationary solutions.