A range-based split in first-order perturbation theory for Lennard-Jones fluids turns the perturbation into a small near-mean-field term whose consistent density and temperature derivatives yield an accurate equation of state.
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Excluded volume and molecular field in the Lennard-Jones fluid: a modified first-order perturbation theory
A range-based split in first-order perturbation theory for Lennard-Jones fluids turns the perturbation into a small near-mean-field term whose consistent density and temperature derivatives yield an accurate equation of state.