The planar-limit Tolman length is derived as a bulk fluctuation observable from second and third moments of the volume distribution in the NPT ensemble, giving -0.7 Å for water at coexistence from SPC/E, TIP4P/2005 simulations and IAPWS-IF97 data.
Equation (C12) provides the forward one-phase thermal-equation-of-state series, whereas Eqs
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Fluctuation-Dissipation Framework for Size-Dependent Surface Tension
The planar-limit Tolman length is derived as a bulk fluctuation observable from second and third moments of the volume distribution in the NPT ensemble, giving -0.7 Å for water at coexistence from SPC/E, TIP4P/2005 simulations and IAPWS-IF97 data.