The competition between persistence length and attraction range controls whether polymer collapse is sharp or gradual, with stiffness promoting collapse for short-range attractions but suppressing it for long-range ones.
Soret Coefficient of Poly(N- isopropylacrylamide)/Water in the Vicinity of Coil- Globule Transition Temperature.Macromolecules2005, 38, 4554-4556
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Collapse of a single polymer chain: Effects of chain stiffness and attraction range
The competition between persistence length and attraction range controls whether polymer collapse is sharp or gradual, with stiffness promoting collapse for short-range attractions but suppressing it for long-range ones.