Defines three fluctuation profiles for energy, entropy, and particle number in inhomogeneous fluids derived via thermodynamic differentiation of density profiles or microscopic covariances, shown to obey Ornstein-Zernike relations in simulations of Lennard-Jones, hard-sphere, and Gaussian-core cases
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Fluctuation profiles in inhomogeneous fluids
Defines three fluctuation profiles for energy, entropy, and particle number in inhomogeneous fluids derived via thermodynamic differentiation of density profiles or microscopic covariances, shown to obey Ornstein-Zernike relations in simulations of Lennard-Jones, hard-sphere, and Gaussian-core cases