A Rayleigh-quotient-based thermodynamic geometry reformulates relaxation dynamics as entropic stiffness versus frictional dissipation, with linear vanishing of the slow relaxation rate near the critical temperature in a van der Waals gas.
Due to parameter degeneration, the volumetric stiffness diverges (−Ξ≈P 2/(RT)∝ ϵ1) according to Eq
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Thermodynamic Geometry of Relaxation
A Rayleigh-quotient-based thermodynamic geometry reformulates relaxation dynamics as entropic stiffness versus frictional dissipation, with linear vanishing of the slow relaxation rate near the critical temperature in a van der Waals gas.