High-resolution spectroscopy of AlF in the X, a, and A states shows its A1Pi-X1Sigma+ transition is rotationally closed with favorable branching ratios, establishing AlF as a practical laser-cooling candidate.
Cold molecules: Progress in Quantum Engineering of Chemistry and Quantum Matter
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abstract
Cooling atoms to ultralow temperatures has produced a wealth of opportunities in fundamental physics, precision metrology, and quantum science. The more recent application of sophisticated cooling techniques to molecules, which has been more challenging to implement due to the complexity of molecular structures, has now opened door to the longstanding goal of precisely controlling molecular internal and external degrees of freedom and the resulting interaction processes. This line of research can leverage fundamental insights into how molecules interact and evolve to enable the control of reaction chemistry and the design and realization of a range of advanced quantum materials.
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Spectroscopic characterization of aluminum monofluoride with relevance to laser cooling and trapping
High-resolution spectroscopy of AlF in the X, a, and A states shows its A1Pi-X1Sigma+ transition is rotationally closed with favorable branching ratios, establishing AlF as a practical laser-cooling candidate.