Mean-field Ising model plus Hill nanothermodynamics predicts first-order transitions in large MOF pores and continuous transitions in small pores, with reduced free-energy barriers and condensation pressures relative to bulk.
Wertheim, Fluids with highly directional attractive forces
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Statistical modeling of equilibrium phase transition in confined fluids
Mean-field Ising model plus Hill nanothermodynamics predicts first-order transitions in large MOF pores and continuous transitions in small pores, with reduced free-energy barriers and condensation pressures relative to bulk.