Rh gem-dicarbonyls on TiO2(110) adopt a square-planar geometry aligned along the [001] direction, as confirmed by STM/nc-AFM, IRAS and DFT, while XPS reveals coexisting IR-invisible Rh clusters.
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Multi-Technique Characterization of Rhodium Gem-Dicarbonyls on TiO$_2$(110)
Rh gem-dicarbonyls on TiO2(110) adopt a square-planar geometry aligned along the [001] direction, as confirmed by STM/nc-AFM, IRAS and DFT, while XPS reveals coexisting IR-invisible Rh clusters.