M-N-Pyrrolic catalysts show higher ammonia TOF than M-N-Pyridinic ones in NO3RR due to distinct scaling relations, with nitrate adsorption/protonation as RDS identified via microkinetic modeling on reported data and confirmed by new experiments.
Atomically Dispersed Unsaturated Cu-N3 Sites on High-Curvature Hierarchically Porous Carbon Nanotube for Synergetic Enhanced Nitrate Electroreduction to Ammonia
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The Key Steps and Distinct Performance Trends of Pyrrolic vs. Pyridinic M-N-C Catalysts in Electrocatalytic Nitrate Reduction
M-N-Pyrrolic catalysts show higher ammonia TOF than M-N-Pyridinic ones in NO3RR due to distinct scaling relations, with nitrate adsorption/protonation as RDS identified via microkinetic modeling on reported data and confirmed by new experiments.