An exact analytical Gaussian-basis formula for the electronic NSI term avoids first-order truncation and shows prior numerical methods overestimate the interaction by over 50% in RaO and 300% in LrF.
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Analytical Representation for the Electronic Contribution of the Nuclear Schiff Interaction Hamiltonian
An exact analytical Gaussian-basis formula for the electronic NSI term avoids first-order truncation and shows prior numerical methods overestimate the interaction by over 50% in RaO and 300% in LrF.