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arxiv: 0801.4650 · v1 · submitted 2008-01-30 · ❄️ cond-mat.str-el

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Electron-phonon interaction in the lamellar cobaltate Na_xCoO₂

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classification ❄️ cond-mat.str-el
keywords electron-phononinteractiondependencephononexperimentallyfrequencyagreesanalyzing
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We study theoretically and experimentally the dependence of the electron-phonon interaction in Na$_x$CoO$_2$ on the sodium concentration $x$. For the two oxygen phonon modes found in Raman experiments, $A_{1g}$ and $E_{1g}$, we calculate the matrix elements of the electron-phonon interaction. Analyzing the feedback effect of the conduction electrons on the phonon frequency we compare the calculated and experimentally observed doping dependence of the $A_{1g}$ mode. Furthermore, due to the momentum dependence of the electron-phonon coupling for the $E_{1g}$ symmetry we find no renormalization of the corresponding phonon frequency which agrees with experiment. Our results shed light on the possible importance of the electron-phonon interaction in this system.

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