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arxiv: 0802.3516 · v1 · submitted 2008-02-24 · ❄️ cond-mat.dis-nn

Can the dynamics of an atomic glass-forming system be described as a continuous time random walk?

classification ❄️ cond-mat.dis-nn
keywords timedynamicscontinuousctrwdescribedrandomsystemterms
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We show that the dynamics of supercooled liquids, analyzed from computer simulations of the binary mixture Lennard-Jones system, can be described in terms of a continuous time random walk (CTRW). The required discretization comes from mapping the dynamics on transitions between metabasins. This comparison involves verifying the conditions of the CTRW as well as a quantitative test of the predictions. In particular it is possible to express the wave vector-dependence of the relaxation time as well as the degree of non-exponentiality in terms of the first three moments of the waiting time distribution.

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