Doping effects in the coupled, two-leg spin ladder BiCu2PO6

We report preparation, x-ray diffraction, magnetic susceptibility chi(T) and heat capacity Cp(T) measurements on the undoped samples as also samples with Zn-doped (S = 0) at Cu site, Ni doped (S = 1) at Cu site, and Ca-doped (holes) at Bi site in the coupled two-leg spin ladder system BiCu2PO6. While, Zn shows complete solid solubility, Ni could be doped to about 20% and Ca to about 15%. Magnetization and heat capacity data in the undoped compound point towards the existence of frustration effects. In all the samples, the chi(T) at low temperature increases with doping content. The Zn-induced susceptibility is smaller than that due to effective S=1/2 moments possibly due to frustrating next-nearest-neighbor interactions along the leg. For Zn content x > 0.01, chi(T) deviates from the Curie-law at low temperatures. The magnetic specific heat data Cm(T) for the Zn-doped samples show weak anomalies at low temperature in agreement with chi(T) behavior. The anomalies are suggestive of spin freezing at low-T. In contrast, prominent effects are observed in chi(T) and Cm(T) on Ni-doped samples. The zero-field-cooled (ZFC) and field-cooled (FC) chi(T) data are different from each other at low temperature unlike that for Zn doped samples, clearly indicating a transition to a spin-glass like phase. No anomalies were found in Ca- or Pb-doped samples.