Charge orderings and phase separations in the atomic limit of the extended Hubbard model with intersite density-density interactions

A simple effective model of charge ordered insulators is studied. The tight binding Hamiltonian consists of the effective on-site interaction U and the intersite density-density interactions Wij (both: nearest-neighbour and next-nearest-neighbour). In the analysis of the phase diagrams we have adopted the variational approach, which treats the on-site interaction term exactly and the intersite interactions within the mean-field approximation. The phase separated states have not been taken into account in previous analyses. Our investigations of two cases of the on-site interaction: attraction (U/(-W_Q)=-10) and repulsion (U/(-W_Q)=1.1) show that, depending on the values of the next-nearest-neighbour attraction, the system can exhibit not only homogeneous phases: charge ordered (CO) and nonordered (NO), but also various phase separated states (CO--NO, CO--CO).