Electrometry near a dielectric surface using Rydberg electromagnetically induced transparency

Electrometry near a dielectric surface is performed using Rydberg electromagnetically induced transparency (EIT). The large polarizability of high n-state Rydberg atoms gives this method extreme sensitivity. We show that adsorbates on the dielectric surface produce a significant electric field that responds to an applied field with a time constant of order one second. For transient applied fields (with a time scale of < 1 s) we observe good agreement with calculations based on numerical solutions of Laplace's equation using an effective dielectric constant to simulate the bulk dielectric.