Spin-Orbital Entangled Excitonic Insulators in (t_(2g))⁴ Correlated Electron Systems

We employ the multi-orbital dynamical mean-field theory to examine the ground state of a three-orbital Hubbard model with a relativistic spin-orbit coupling (SOC) at four electrons per site. We demonstrate that the interplay between the strong electron correlations and the SOC induces a Van Vleck-type nonmagnetic insulator and its magnetic exciton condensation. We also find in the moderate electron correlation regime that the SOC induces another type of a nonmagnetic excitonic insulator, in addition to a relativistic band insulator. The characteristic features among these insulators are manifested in the momentum resolved single-particle excitations, thus accessible by angle-resolved photoemission spectroscopy experiments.