Terahertz Spin-Orbital Excitations in the paramagnetic state of multiferroic Sr₂FeSi₂O₇

We studied the novel multiferroic material Sr$_2$FeSi$_2$O$_7$, and found 3 absorption modes above the magnetic ordering transition temperature using time-domain terahertz spectroscopy. These absorption modes can be explained as the optical transitions between the spin-orbit coupling and crystal field split 3d$^6$ Fe$^{2+}$ ground state term in this material. Consideration of the compressed tetrahedral environment of the Fe$^{2+}$ site is crucial to understand the excitations. We point out, however, discrepancies between the single-site atomic picture and the experimental results.