Leading order relativistic corrections to the dipole polarizability of the hydrogen molecular ions
classification
⚛️ physics.atom-ph
keywords
hydrogenionsmolecularorderpolarizabilitycorrectionsdipoleleading
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The static dipole polarizability for the hydrogen molecular ions H$_2^+$, HD$^+$, and D$_2^+$ are calculated. These new data for polarizability takes into account the leading order relativistic corrections to the wave function of the three-body system resulted from the Breit-Pauli Hamiltonian of $m\alpha^4$ order. Our study covers a wide range of rotational ($L=0-5$) and vibrational ($v=0-10$) states, which are of practical interest for precision spectroscopy of the hydrogen molecular ions.
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