Single crystal growth and physical properties of 50% electron doped rhodate Sr_(1.5)La_(0.5)RhO₄
classification
❄️ cond-mat.str-el
keywords
singlecrystalx-raycrystalselectronmeasurementsoctahedraltemperature
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Centimeter-sized single crystals of Sr$_{1.5}$La$_{0.5}$RhO$_{4}$ were grown by the floating zone method at oxygen pressures of 20~bar. The quality of our single crystals was confirmed by X-ray Laue, powder and single crystal X-ray diffraction, neutron and X-ray absorbtion spectroscopy measurements. At $\sim$50% electron doping we observe RhO$_3$ octahedral rotations of $\sim$8.2$^{\circ}$ within the octahedral basal plane which are incompatible with space group I4/mmm. Our single crystal was further characterized by susceptibility, electrical transport and, finally, specific heat measurements showing a temperature dependent Debye temperature.
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