Evidence for breathing-type pseudo Jahn-Teller distortions in the charge density wave phase of 1T-TiSe₂

The charge density wave (CDW) phase in 1$T$-TiSe$_2$ is investigated using angle resolved photoemission spectroscopy (ARPES) and neutron scattering measurements. Our ARPES results reveal a clear temperature dependence of the chemical potential of the system. They also demonstrate specific changes encountered by the Se 4$p$ valence and Ti 3$d$ conduction bands as the temperature of the system is decreased through $T_{\text{CDW}}$. The valence band undergoes a downward shift, whereas the conduction band remains unaffected. The crystal structure in the CDW state shows a distinct split of the Ti-Se atomic correlations that are reminiscent of Jahn-Teller distortions, manifested in a breathing-type mode. The ARPES data together with the local structure analysis support a direct link between Jahn-Teller-like distortions and the CDW order in 1$T$-TiSe$_2$.