Lattice Opening Upon Bulk Reductive Covalent Functionalization of Black Phosphorus

Stefan Wild , Michael Fickert , Aleksandra Mitrovic , Vicent Lloret , Christian Neiss , Jos\'e Alejandro Vidal- Moya , Miguel \'Angel Rivero-Crespo , Antonio Leyva-P\'erez

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Katharina Werbach Herwig Peterlik Mathias Grabau Haiko Wittk\"amper Christian Papp Hans-Peter Steinr\"uck Thomas Pichler Andreas G\"orling Frank Hauke Gonzalo Abell\'an Andreas Hirsch

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classification ⚛️ physics.app-ph

keywords functionalizationcovalentreductiveblackbulkphosphorusachievedactivation

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The chemical bulk reductive covalent functionalization of thin layer black phosphorus (BP) using BP intercalation compounds has been developed. Through effective reductive activation, covalent functionalization of the charged BP is achieved by organic alkyl halides. Functionalization was extensively demonstrated by means of several spectroscopic techniques and DFT calculations, showing higher functionalization degrees than the neutral routes.

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Lattice Opening Upon Bulk Reductive Covalent Functionalization of Black Phosphorus

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