Doppler-free Rydberg Spectroscopy in Warm Vapor

The common approach for producing Rydberg atoms in warm vapor cells is with lasers arranged in a counter-propagating, collinear configuration. Doppler effects in these configurations reduce the efficiency of excitation to the Rydberg state while also producing broadened spectral features. In this work, we demonstrate a three-laser Doppler-free excitation using laser beams whose k-vectors sum to zero, resulting in an enhancement in the Rydberg density and narrowed spectral features. A three-times enhancement to Rydberg density along with a near four-times reduction in spectroscopic line-widths are observed compared to a collinear configuration. This Doppler-free configuration could prove beneficial to Rydberg atomic technologies, such as electric field sensing with small volumes or deterministic photon sources.