Ar I as a tracer of ionization evolution

We present a study of Ar abundances in 15 damped Ly alpha systems (DLAs) in the redshift interval from 2.3 to 3.4. The sample includes 4 new UVES/VLT measurements of Ar I column densities. The majority of DLAs show significant underabundances of Ar relative to other alpha-capture elements with common nucleosynthetic origin. We show that neither dust depletion nor intervening HII regions inside DLAs offer a viable justification to these underabundances. A natural explanation is found in the framework of photoionization models of HI regions embedded in an ionizing continuum with varying spectral distribution. At z ~ 2.5 the observed Ar deficiencies are large, [Ar/alpha] ~ -0.6/-0.8 dex, suggestive of a hard, QSO-dominated spectrum. At z >~ 3 the deficiencies are instead small, suggestive of a soft, stellar-type spectrum, though more data are needed to generalize this high-z result. We argue that the change of Ar abundances is induced by the evolution of the UV metagalactic continuum, in which case the UV emission internal to DLAs must be small (i.e. DLAs should have modest star formation rates) and the external background must become softer at z > 3. The former requirement is consistent with the modest evolution of DLAs abundances and the lack of Ly_alpha and H_alpha emissions associated with DLAs. The latter requirement is consistent with the observed evolution of SiIV/CIV ratios in the IGM, the claims of high escape fraction of UV photons from Ly-break galaxies at z >~ 3, and the recent finding that the HeII re-ionization seems to occur between z ~ 3.4 and z ~ 3. From the comparison with local interstellar studies, we predict a rise of Ar abundances in the redshift range from z ~ 2.3 to z=0, at the epoch at which the metagalactic field of galaxies overcomes that of quasars.