Potential Variations in the Interstellar N I Abundance

We present Far Ultraviolet Spectroscopic Explorer (FUSE) and Space Telescope Imaging Spectrograph observations of the weak interstellar N I doublet at 1160 Angstroms toward 17 high-density sight lines [N(Htot)>=10^21 cm^-2]. When combined with published data, our results reveal variations in the fractional N I abundance showing a systematic deficiency at large N(Htot). At the FUSE resolution (~20 km s^-1), the effects of unresolved saturation cannot be conclusively ruled out, although O I at 1356 Angstroms shows little evidence of saturation. We investigated the possibility that the N I variability is due to the formation of N_2 in our mostly dense regions. The 0-0 band of the c'_4 ^1Sigma^+_u - X ^1Sigma^+_g transition of N_2 at 958 Angstroms should be easily detected in our FUSE data; for 10 of the denser sight lines, N_2 is not observed at a sensitivity level of a few times 10^14 cm^-2. The observed N I variations are suggestive of an incomplete understanding of nitrogen chemistry. Based on observations made with the NASA-CNES-CSA Far Ultraviolet Spectroscopic Explorer, which is operated for NASA by the Johns Hopkins University under NASA contract NAS 5-32985, and the NASA/ESA Hubble Space Telescope, obtained from the Multimission Archive at the Space Telescope Science Institute, which is operated by the Association of Universities for Research in Astronomy, Inc., under the NASA contract NAS 5-26555.