Detection of the 62 micron Crystalline Water Ice Feature in Emission toward HH7 with ISO-LWS

We report the detection of the 62 micron feature of crystalline water ice in emission towards the bow-shaped Herbig-Haro object HH 7. Significant amounts of far infrared continuum emission are also detected between 10 and 200 micron, so that Herbig-Haro objects cease to be pure emission-line objects at FIR wavelengths. The formation of crystalline water ice mantles requires grain temperatures T > 100 K at the time of mantle formation, suggesting that we are seeing material processed by the HH 7 shock front. The deduced ice mass is \~2e-5 solar masses corresponding to a water column density N~ 1e18 cm-3; an estimate of the [H2O]/[H] abundance yields values close to the interstellar gas-phase oxygen abundance. The relatively high dust temperature and the copious amounts of gas-phase water needed to produce the observed quantity of crystalline water ice, suggest a scenario where both dissociative and non-dissociative shocks co-exist. The timescale for ice mantle formation is of the order of ~400 years, so that the importance of gas-phase water cooling as a shock diagnostic may be greatly diminished.