LiVGe2O6, an anomalous quasi 1D, S = 1 system, as revealed by NMR

We report the results of $^{7}$Li nuclear magnetic resonance (NMR) studies of LiVGe$_{2}$O$_{6}$, a quasi one--dimensional spin $S = 1$ model system, at low temperatures. Our data, including NMR spectra and the temperature dependence of the spin-lattice relaxation rate $T_{1}^{-1}$, indicate a first order phase transition to occur at $T_{c}\simeq 23$ K. The NMR response of LiVGe$_{2}$O$_{6}$ below $T_{c}$ suggests that the ordered phase is antiferromagnetic and has unusual features. Possible reasons for this unexpected behavior are discussed.