Towards an understanding of CMR pyrochlore Tl2Mn2O7

Tl2Mn2O7 exhibits important differences with other colossal magnetoresistance (CMR) compounds, like the Mn-perovskites, in its crystal structure and electronic properties, indicating the possibility of different mechanisms for CMR being present. The larger experimental background now existent, has received diverse interpretations. We aim to contribute to the understanding of the properties of Tl2Mn2O7 through the study of a generic model for the compound, including Hund and superexchange couplings as well as hybridization effects. It includes two kinds of electronic orbitals, as widely believed to be present: one, directly related to magnetism, involving localized Mn magnetic moments, and a narrow band strongly Hund-coupled to them. Also, more extended electronic orbitals, related to the carriers in Tl2Mn2O7, appear and hybridize with the narrow band. The possibility of a superexchange coupling between the localized spins is also allowed for. This generic model allows exploration of many of the proposals put forward by other researchers for Tl2Mn2O7. As a first approach to the problem, we study the phase diagram and electronic structure employing simplifications, for sets of parameters including previous suggestions for the compound. Furthermore, we are able to exhibit similarities with results obtained in 1997 using an intermediate valence model for Tl2Mn2O7, in particular, for the electronic structure in the ferromagnetic phase.