Magnetic Structure and Properties of the S = 5/2 Triangular Antiferromagnet α-NaFeO₂

The magnetic properties of $\alpha$-NaFeO$_2$ are studied by neutron diffraction and magnetization measurements. An ordered phase with spins aligned along the b$_hex$ axis exists at low temperatures (T < 4 K). At intermediate temperatures (4 K < T < 11 K), the system passes through an incommensurate ordered phase before transforming into a short range ordered state at higher temperatures that persists up to at least 50 K. Although the short range ordering does not persist to room temperature according to neutron diffraction, the magnetic susceptibility does not follow Curie-Weiss behavior, even up to 320 K. This rich magnetic behavior can be understood qualitatively as a competition between different magnetic exchange interactions that are similar in magnitude. The delicate balance between these interactions makes $\alpha$-NaFeO$_2$ a candidate for more detailed theoretical work to understand magnetic behavior in frustrated magnetic systems.