Polaronic signature in the metallic phase of La0.7Ca0.3MnO3 films detected by scanning tunneling spectroscopy

In this work we map tunnel conductance curves with nanometric spatial resolution, tracking polaronic quasiparticle excitations when cooling across the insulator-to-metal transition in La0.7Ca0.3MnO3 films. In the insulating phase the spectral signature of polarons, a depletion of conductance at low bias flanked by peaks, is detected all over the scanned surface. These features are still observed at the transition and persist on cooling into the metallic phase. Polaron-binding energy maps reveal that polarons are not confined to regions embedded in a highly-conducting matrix but are present over the whole field of view both above and below the transition temperature.