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arxiv: physics/0310141 · v1 · submitted 2003-10-28 · ⚛️ physics.atom-ph

Finite-field evaluation of the Lennard-Jones atom-wall interaction constant C₃ for alkali-metal atoms

classification ⚛️ physics.atom-ph
keywords alkali-metalatomsconstantfinite-fieldinteractionlennard-jonesappliedapproximation
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A finite-field scaling method is applied to evaluate the Lennard-Jones interaction constant C_3 for alkali-metal atoms. The calculations are based on the relativistic single-double (SD) approximation in which single and double excitations of Dirac-Hartree-Fock wave functions are included to all orders in perturbation theory.

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