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arxiv: physics/0603232 · v1 · submitted 2006-03-28 · ⚛️ physics.atom-ph

Long-range interactions for He(n S)--He(n' S) and He(n S)--He(n' P)

classification ⚛️ physics.atom-ph
keywords long-rangestatesatomcalculatedcoefficientscoordinatescorrelatedeffects
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The energetically lowest five states of a helium atom are: He($1^1S$), He($2^3S$), He($2^1S$), He($2^3P$), and He($2^1P$). Long-range interaction coefficients $C_3$, $C_6$, $C_8$, $C_9$, and $C_{10}$ for all $S-S$ and $S-P$ pairs of these states are calculated precisely using correlated wave functions in Hylleraas coordinates. Finite nuclear isotope mass effects are included.

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