Speed-gradient principle for nonstationary processes in thermodynamics
classification
⚛️ physics.gen-ph
keywords
principleentropyspeed-gradientdynamicsnonstationarysg-principlesystemstransient
read the original abstract
The speed-gradient variational principle (SG-principle) is formulated and applied to thermodynamical systems. It is shown that Prigogine's principle of minimum entropy production and Onsager's symmetry relations can be interpreted in terms of the SG-principle and, therefore, are equivalent to each other. In both cases entropy of the system plays a role of the goal functional. The speed-gradient formulation of thermodynamic principles provide their extended versions, describing transient dynamics of nonstationary systems far from equilibrium. As an example a model of transient (relaxation) dynamics for maximum entropy principle is derived.
This paper has not been read by Pith yet.
discussion (0)
Sign in with ORCID, Apple, or X to comment. Anyone can read and Pith papers without signing in.