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Universal rate constants for reactive collisions of ultracold molecules

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arxiv 0912.0370 v2 pith:2MAXOBLJ submitted 2009-12-02 physics.atom-ph

classification physics.atom-ph
keywords ultracoldcollisionsconstantsmodelmoleculesratecollisiongives
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A simple quantum defect model gives analytic expressions for the complex scattering length and threshold collision rates of ultracold molecules. If the probability of reaction in the short-range part of the collision is high, the model gives universal rate constants for s- and p-wave collisions that are independent of short-range dynamics. This model explains the magnitudes of the recently measured rate constants for collisions of two ultracold 40K87Rb molecules, or an ultracold 40K atom with the 40K87Rb molecule [Ospelkaus et al., Science 327, 853 (2010)].

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