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Thermal and magnetic properties of a low-temperature antiferromagnet Ce$_4$Pt$_{12}$Sn$_{25}$

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arxiv 1009.0201 v2 pith:RWNP57KJ submitted 2010-09-01 cond-mat.str-el

classification cond-mat.str-el
keywords anomalyheisenbergkondomagneticmagnetizationmodelstatetemperature
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abstract

We report specific heat ($C$) and magnetization ($M$) of single crystalline Ce$_4$Pt$_{12}$Sn$_{25}$ at temperature down to $\sim$50mK and in fields up to 3T. $C/T$ exhibits a sharp anomaly at 180mK, with a large $\Delta C/T\sim$30J/molK$^2$-Ce, which, together with the corresponding cusp-like magnetization anomaly, indicates an antiferromagnetic (AFM) ground state with a N\'eel temperature $T_N$=180mK. Numerical calculations based on a Heisenberg model reproduce both zero-field $C$ and $M$ data, thus placing Ce$_4$Pt$_{12}$Sn$_{25}$ in the weak exchange coupling $J<J_c$ limit of the Doniach diagram, with a very small Kondo scale $T_K\ll T_N$. Magnetic field suppresses the AFM state at $H^*\approx$0.7T, much more effectively than expected from the Heisenberg model, indicating additional effects possibly due to frustration or residual Kondo screening.

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