The effects of snowlines on C/O in planetary atmospheres

The C/O ratio is predicted to regulate the atmospheric chemistry in hot Jupiters. Recent observations suggest that some exo-planets, e.g. Wasp 12- b, have atmospheric C/O ratios substantially different from the solar value of 0.54. In this paper we present a mechanism that can produce such atmospheric deviations from the stellar C/O ratio. In protoplanetary disks, different snowlines of oxygen- and carbon-rich ices, especially water and carbon monoxide, will result in systematic variations in the C/O ratio both in the gas and in the condensed phase. In particular, between the H2O and CO snowlines most oxygen is present in icy grains - the building blocks of planetary cores in the core accretion model - while most carbon remains in the gas-phase. This region is coincidental with the giant-planet forming zone for a range of observed protoplanetary disks. Based on standard core accretion models of planet formation, gas giants that sweep up most of their atmospheres from disk gas outside of the water snowline will have C/O?1, while atmospheres significantly contaminated by evaporating planetesimals will have stellar or sub-stellar C/O when formed at the same disk radius. The overall metallicity will also depend on the atmosphere formation mechanism, and exoplanetary atmospheric compositions may therefore provide constraints on where and how a specific planet formed.