Study of the possibility of eliminating the Gibbs paradox within the framework of classical thermodynamics

V. Ihnatovych

Study of the possibility of eliminating the Gibbs paradox within the framework of classical thermodynamics

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arxiv 1306.5737 v1 pith:22WSEZNK submitted 2013-06-21 physics.hist-ph

V. Ihnatovych This is my paper · ORCID

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keywords thermodynamicsclassicalentropyformulasframeworkgasesgibbsideal

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The formulas for the entropy of ideal gases mixture and the entropy change in mixing of ideal gases on the basis of the third law of thermodynamics were obtained. It is shown that when using these formulas, the Gibbs paradox within the framework of classical thermodynamics does not arise.

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Solving the Gibbs Paradox by Local Free Space and Collision Potential
cond-mat.stat-mech 2026-08 reject novelty 4.0 of 10

The paper derives a new formula for gas-mixture entropy increase that depends on molecular properties, but the derivation contains algebraic errors and predicts negative entropy for common gas pairs.

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